Sorry, had to ask as you have not mentioned in your post...Plus, see if your VLC is latest one.
Secondly, try downloading latest codecs from Free-Codecs.com and try opening file in Classic Media Player (although is second to VLC)
you must have downloaded in parts n its name remains FLV1.
so remove 1 from the FLV1 and it will be OK.
if you dont know how to remove that 1 then follow this for XP.
open my computer =>>Tools Menu =>> Folder Option =>>
View =>> then find option " Hide Extensions for known file types " uncheck it n rename your file.
dont forget to check mark " Hide Extensions for known file types " this option again.